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Researchers from Tokyo Metropolitan University have shown that the tunable hydrophobic nature of dense siloxane gels is strongly correlated with their catalytic activity, explicitly demonstrating how molecules with different hydrophobic nature at the molecular level interact differently with surfaces of differing hydrophobicity. This is also the first time a siloxane gel has been shown to be highly effective for the reaction of silyl ethers, commonly used as a protecting agent.
A hydrophobic material is one which repels water. Household examples include coatings for non-stick frying pans and smartphones. Hydrophobicity also plays a key role in nature, for example, in mechanisms by which certain plants and animals harvest water from the atmosphere, and the packing of DNA into chromosomes. In recent years, it has also been revealed to be part of the function of acid catalysts, acidic materials that can speed up chemical reactions, widely used in the petrochemical industry. Though it was widely known that more hydrophobicity led to better catalysis, it was not clear why this was the case due to the heterogeneous porous structure of the most common catalysts.
Group - Researchers - Dr - Hiroki - Miura
Thus, a group of researchers led by Dr. Hiroki Miura and Prof Tetsuya Shishido from Tokyo Metropolitan University studied the catalytic activity of a dense siloxane gel, a kind of silicone rubber, with acidic sulfo groups attached. Importantly, these gels can be covered with controlled amounts of both acid groups and hydrophobic methyl groups, enabling fine control of hydrophobicity. These gels are also not porous, presenting a surface that...
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