Controlling organic semiconductor band gaps by electron-acceptor fluorination

ScienceDaily | 10/17/2018 | Staff
TwiztedGurl (Posted by) Level 3
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"Electron-accepting units are important elements of organic semiconductors," study corresponding author Yoshio Aso says. "Through the controlled addition of electronegative fluorine groups to a widely used electron-accepting material, we were able to show precise control of the energy levels within the resulting semiconductor. This ability to tune the band gap translates to selectivity over the injection and transport of holes and/or electrons within the material, which is important in potential applications."

The fluorinated electron-acceptor unit was used to prepare a thin film solar cell that was compared with a cell based on a non-fluorinated analogue. The researchers found that the fluorinated material showed enhanced power conversion efficiency, up to 3.12%. The morphology of the fluorinated film was also found to be good, which supported...
(Excerpt) Read more at: ScienceDaily
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