Click For Photo: https://3c1703fe8d.site.internapcdn.net/newman/gfx/news/hires/2018/3delectronmi.jpg
Careful sample preparation, electron tomography and quantitative analysis of 3-D models provides unique insights into the inner structure of reverse osmosis membranes widely used for salt water desalination wastewater recycling and home use, according to a team of chemical engineers.
These reverse osmosis membranes are layers of material with an active aromatic polyamide layer that allows water molecules through, but screens out 99 to 99.9 percent of the salt.
Water - Stresses - Membrane - Filtration - Materials
"As water stresses continue to grow, better membrane filtration materials are needed to enhance water recovery, prevent fouling, and extend filtration module lifetimes while maintaining reasonable costs to ensure accessibility throughout the world," said Enrique Gomez, professor of chemical engineering, Penn State. "Knowing what the material looks like on the inside, and understanding how this microstructure affects water transport properties, is crucial to designing next-generation membranes with longer operational lifetimes that can function under a diverse set of conditions."
Gomez and his team looked at the internal structure of the polyamide film using high-angle annular dark field scanning transmission electron microscopy (HAADF-STEM) tomography. HAADF-STEM's image intensity is directly proportional to the density of the material, allowing mapping of the material to nanoscale resolution.
Density - Polyamide - Layer - Gomez - Varies
"We found that the density of the polyamide layer is not homogeneous," said Gomez. "But instead varies throughout the film and, in this case, is highest at the surface."
This discovery changes the way the engineers think about how water moves through this material, because the resistance to flow is not homogeneous and is highest at the membrane surface.
HAADF-STEM - Researchers - Models - Membrane - Structure
HAADF-STEM allowed the researchers to construct 3-D models of the membrane's internal structure....
Wake Up To Breaking News!
If you're not living on the edge, you're taking up too much room.